Carbon Nanotube Material Removes 99 Percent Of Heavy Metals From Water





Environment, 03 Aug - 2017 ,

Carbon Nanotube Material Removes 99 Percent Of Heavy Metals From Water
Plain quartz fiber, top, gains the ability to remove toxic metals from water when carbon nanotubes are added, bottom. Credit: Barron Research Group/Rice University

Carbon nanotubes immobilized in a tuft of quartz fiber have the power to remove toxic heavy metals from water, according to researchers at Rice University.

Carbon nanotubes immobilized in a tuft of quartz fiber have the power to remove toxic heavy metals from water, according to researchers at Rice University.

Prize-winning filters produced in the lab of Rice chemist Andrew Barron by then-high school student and lead author Perry Alagappan absorb more than 99 percent of metals from samples laden with cadmium, cobalt, copper, mercury, nickel and lead. Once saturated, the filters can be washed with a mild household chemical like vinegar and reused.

The researchers calculated one gram of the material could treat 83,000 liters of contaminated water to meet World Health Organization standards  enough to supply the daily needs of 11,000 people.

The lab's analysis of the new filters appears this month in Nature's open-access Scientific Reports.

The robust filters consist of carbon nanotubes grown in place on quartz fibers that are then chemically epoxidized. Lab tests showed that scaled-up versions of the "supported-epoxidized carbon nanotube" (SENT) filters proved able to treat 5 liters of water in less than one minute and be renewed in 90 seconds. The material retained nearly 100 percent of its capacity to filter water for up to 70 liters per 100 grams of SENT, after which the metals contained could be extracted for reuse or turned into a solid for safe disposal.

While the quartz substrate gives the filter form and the carbon nanotube sheath makes it tough, the epoxidation via an oxidizing acid appears to be most responsible for adsorbing the metal, they determined.

Alagappan, now an undergraduate student at Stanford University, was inspired to start the project during a trip to India, where he learned about contamination of groundwater from the tons of electronic waste  phones, computers and the like  that improperly end up in landfills.

 Raw materials for the filter are inexpensive and pointed out the conversion of acetic acid to vinegar is ubiquitous around the globe, which should simplify the process of recycling the filters for reuse even in remote locations. This would make the biggest social impact on village-scale units that could treat water in remote, developing regions.


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